此反应的机理研究报道于【Bulletin of the Chemical Society of Japan, 1981, 54, 793-799】
反应操作
To a stirred solution of 4-chlorobenzonitrile (1.37 g, 0.01 mol) in DMSO (3 ml), cooled in a ice bath, was added 30% H2O2 (1.2 ml) and K2CO3, the reaction was allowed to warm up to r.t. (strong exothermic effect was observed). After 5 min., distilled water (50 ml) was added, cooling applied, and the product was collected by filtration, yield 85%.
参考资料
1、J. Am. Chem. Soc. 1979, 101, 1291–1293
2、Bulletin of the Chemical Society of Japan, 1981, 54, 793-799
3、Synthesis 1989, 949
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